First, I would just copy parts of it:
Documents and Settings/Your_name\Cookies
Documents and Settings\Your_name/Your_name\Favorites
Documents and Settings\Your_name\Local Settings\Application Data\Microsoft\Outlook (or wherever your email and address book are located)
C:\Documents and Settings\Your_name\My Documents
If you copy the whole Documents and Settings folder, you'll end up with junk you don't need, and several files that can't be copied (NTUSER.DAT, NTUSER.DAT.LOG, INDEX.DAT are a few).
Documents and Settings/Your_name\Cookies
Documents and Settings\Your_name/Your_name\Favorites
Documents and Settings\Your_name\Local Settings\Application Data\Microsoft\Outlook (or wherever your email and address book are located)
C:\Documents and Settings\Your_name\My Documents
If you copy the whole Documents and Settings folder, you'll end up with junk you don't need, and several files that can't be copied (NTUSER.DAT, NTUSER.DAT.LOG, INDEX.DAT are a few).